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〈参考文献〉

[1] “Cyclic Triolborates: Air- and Water-Stable Ate Complexes of Organoboronic Acids”

Yamamoto, Y., Takizawa, M., Yu, X.-Q., Miyaura, N. : Angew. Chem. Int. Ed. 2008,  47, 928. DOI: 10.1002/anie.200704162

A borate in the hand is a convenient reagent for palladium- and copper-catalyzed CC and CN bond-forming reactions, especially when, like the title bench-stable complexes, it demonstrates high transmetalation efficiency. Cyclic triolborates can be synthesized readily from organoboronic acids (see scheme), can be handled and stored without special precautions, and are relatively soluble in organic solvents.

 

[2]”Cyclic Triolborate Salts: Novel Reagent for Organic Synthesis”

Yamamoto,Y. : Heterocycles, 2012, 85, 799 –819. DOI: 10.3987/REV-12-728

This review summarizes metal-catalyzed C-C and C-N bond-forming reactions using novel heteroaryltriolborate salts for palladium- or copper-catalyzed cross-coupling reactions with arylhalides or amines and for rhodium-catalyzed addition reactions to α,β-unsaturated carbonyl compounds or imines.

[3] 山本 靖典, 宮浦 憲夫: 和光純薬時報, 76, No.2 (2008).　Link

 

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